Chloroacetyl chloride reacts vigorously with water to generate gaseous hcl. Handling and storage protect against physical damage. Our msds database is an easy to use, do it yourself tool, and best of all. Chloroacetyl chloride was used to study the in vitro metabolism of chloroacetamide. Based on a scenario where the chemical is spilled into an excess of water at least 5 fold excess of water, half of the maximum theoretical yield of hydrogen chloride gas will be created in 1. However, the samples can not be stored for more than 10 days without significant degradation, even with freezing. If released to the atmosphere, acetyl acetone is expected to exist in the vapor phase. Fedex ground hazardous materials table please refer to the. It undergoes violently hydrolysis in presence of atmospheric moisture. Precautionary statements p210 keep away from heat, hot. Find msds or sds, a coa, data sheets and more information.
Acetyl chloride reacts vigorously with water to generate gaseous hcl. Vaporphase acetyl acetone is expected to degrade by reaction with photochemically produced hydroxyl radicals estimated halflife of 14 days. Based on a scenario where the chemical is spilled into an excess of water at least 5 fold excess of water, half of the maximum theoretical yield of hydrogen chloride gas will be created in 0. Chloroacetyl chloride is on the hazardous substance. Acetyl chloride undergoes reaction with decalin and aluminum trichloride to afford a tricyclic enol ether. Skin contact wash off immediately with plenty of water for at least 15 minutes. Chloroacetyl chloride can be used for chloroacetylation and chemical modification of poly glycidyl methacrylate. Store in a cool, dry wellventilated location, away from any area where the fire hazard may be acute. It promotes the cyclopropanation of alkene with dibromomethane or diiodomethane in the presence of zn dust and copper chloride in ether. Material safety data sheet date last revised 02182009 by m.
Chloroacetyl chloride causes the acylation of cyanopyrazoline during the synthesis of secondary aminesubstituted cyanopyrazoline derivatives. Acetyl chloridemethanol as a convenient reagent for. Wear splash resistant safety goggles with a faceshield. Acetyl chloride cas no 75365 material safety data sheet sds msds. C2h2cl2o, clch2cocl, acetyl chloride, chloro, chloroacetic acid chloride, chloroacetic chloride. Monoclonal antibody trial size samples click here for a free sample home. H226 flammable liquid and vapor h302 harmful if swallowed. Reason for citation dichloroacetyl chloride is on the hazardous substance list because it is cited by dot and nfpa. Dichloroacetyl chloride is a reactive chemical and a dangerous explosion hazard. It is recognized that ketene and acetyl chloride will also react. However, we make no warranty of merchantability or any other warranty, express or.
This material does not contain any class 1 ozone depletors. This material does not contain any hazardous air pollutants. Acetyl acetone material safety data sheet cas no 123546. Identification product name acetyl chloride cat no.
Incompatible with strong bases, alcohols,strong oxidizing agents. Acetonesoluble cellulose acetates prepared by onestep. Phenylacetyl chloride is used as a key precursor in the total synthesis of vialinin b. Chloroacetyl chloride, chloroacetyl chloride 98%, supply chloroacetyl chloride,best quality chloroacetyl chloride. It is employed as a linker to prepare dendrimers and also used in the synthesis of various conjugated aromatic small molecules. Show this safety data sheet to the doctor in attendance. Any selfcontained breathing apparatus that has a full facepiece and is operated in a pressuredemand or other positivepressure mode. Chemtrec 8004249300 outside usa 7035273887 1216 6th ave n kent wa 98032 phone. Your new online msds binder is a place for you to store the material safety data sheets you need to deploy. Commercially available as oil concentrate and as dust concentrate. First aid measures remove victim to fresh air and keep at rest in a position comfortable for breathing. Acetyl acetone cas no 123546 material safety data sheet sds msds. Ac151270000, ac151270010, ac151270025, ac151275000, ac219470000, ac219470250, ac219472500, a27250 synonyms. P261 avoid breathing dust fume gas mist vapours spray.
This chemical is considered hazardous by the 2012 osha hazard. It is used as a tear gas and to make other chemicals. Sds of acetyl chloride, safety data sheets, cas 75365. First aid measures general advice consult a physician. Acetyl acetone peroxide with more than 9 percent by mass active oxygen forbidden acetyl benzoyl peroxide, solid, or with more than 40. Uses advised against food, drug, pesticide or biocidal product use details of the supplier of the safety data sheet. Material description company issue dateflannery, incorporated november 2007.
Acetyl chloride material safety data sheet cas no 75365. Safety data sheet according to 29cfr19101200 and ghs rev. Ib2, t8, tp2 154 202 acetyl chloride 3, 8 un1717 ii flammable liquid, corrosive a3, a7, ib1, n34, t8, tp2 150 202 acetyl cyclohexanesulfonyl peroxide, with more than. Acetyl chloride, reagent grade, 98% ch3cocl sigmaaldrich. Methylene chloride revision date 28nov2019 eye contact rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Chloro acetyl chloride cas no 79049 material safety data sheet sds msds. Safety data sheet creation date 07sep2010 revision date 25apr2019 revision number 6 1. View or download the acetyl chloride msds material safety data sheet or sds for 822252 from merck. Safety data sheet northwest missouri state university. Acetyl chloride is a clear, corrosive and fuming liquid. You can obtain copies of sampling results from your employer. Ou chemical safety data no longer updated more details.
A27250 casno 75365 synonyms ethanoyl chloride certified recommended use laboratory chemicals. Articles of chloroacetyl chloride are included as well. It has been reported that acetyl chloride can be used as a fluorescence histochemical in combination with formaldehyde to identify tryptophylpeptidecontaining endocrine cells of the hypophysis. Chlorophacinone is a diarylmethane and a betatriketone. Lysozyme from chicken egg white l6876 sigmaaldrich. If inhaled if breathed in, move person into fresh air. A quantitative formation of amine hydrochlorides, b carboxylate ester formation, c mild removal of nbocprotective group. Acetyl chloride is an acid chloride reagent used for acetylation in organic synthesis reactions such as esterification and the friedelcrafts reaction. Section 1 chemical product and company identification product name chloroacetyl chloride statement of hazardous nature considered a hazardous substance according to osha 29 cfr 1910. Buy 2,6dimethylphenoxyacetylchloride cas 20143480, a biochemical for proteomics research, from santa cruz. Chemical sampling information database on chloroacetyl chloride. Affinisol hpmcas for spraydried dispersion sdd solving. Chloroacetyl chloride is a colorless to yellow liquid with a strong odor. Identification dichloroacetyl chloride is a fuming liquid with a sharp, penetrating odor.
Affinisol hpmcas for spraydried dispersion sdd hpmcas to the solution to give a clear to slightly opaque final solution with 25 wt% api to 75 wt% affinisol hpmcas ratio. Identification of the substancemixture and of the companyundertaking. Without using any catalyst, cornhusk cellulose acetates ccas with the degree of substitution ds in a range from 2. Other companies are charging thousands of dollars to set up accounts and give you access to their msds online database. Chloro acetyl chloride material safety data sheet cas no. Sigmaaldrich offers a number of acetyl chloride products. Cellulose samples extracted from cornhusk have been successfully acetylated in an ionic liquid 1allyl3methylimidazolium chloride amimcl. Pdf acetyl chloridemethanol as a convenient reagent for. Provide an emergency eye wash fountain and quick drench shower in. Canadian ingredient disclosure list section 16 additional information msds creation date.